Toyoda Gosei Co., Ltd. Toyoda Gosei Co., Ltd.

Environmentally-friendly water purification.
From mercury lamps to disinfecting LEDs

2024.09.27

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Mercury was once widely used in pesticides because of its superior disinfecting and sterilizing effect. However, following Minamata disease and other problems it became clear that mercury is a harmful substance that causes health damage and environmental destruction. The international “Minamata Convention on Mercury” agreement in 2017 forbids the mining of mercury and places restrictions on the manufacturing of fluorescent lamps, batteries and other products using mercury, as well as their import and export.* However, the use of mercury vapor lamps for disinfection in water and sewerage systems is still allowed under proper management since there is no substitute for those lamps.Since UV-C (deep ultraviolet) LEDs are effective in eliminating viruses and bacteria, Toyoda Gosei is developing and proposing high performance UV-C LEDs and disinfecting products for a mercury-free society.

*The manufacture and export/import of fluorescent tube lights will be prohibited by the end of 2027 (use and sales still allowed), while the manufacture and export/import of button cell batteries and cosmetics that use mercury, and polyurethane that uses mercury-containing catalysts, will be prohibited by the end of 2025

01Rising expectations for UV-C LEDs

UV (ultraviolet radiation) is light that has short wavelengths of less than 400 nanometers (one billionth of a meter). Among UV, light with short wavelengths of 280–100 nanometers is called UV-C (deep ultraviolet), and this light acts to cleave the DNA chain of microorganisms so that they are no longer viable (inactivation).
In addition to not using mercury, UV-C LEDs have features including more instantaneous lighting, operation at lower voltages, and greater compactness than mercury lamps. They are promising for use in medicine, agriculture and various other fields. They are also used in disinfection in places such as water treatment plants, and can eliminate Cryptosporidium, a toxic microorganism against which chlorine is ineffective. Thus, expectations for their use in providing safe water are also rising.

■What is UV-C (deep ultraviolet)?
Deep ultraviolet radiation denatures genetic information and so is effective in eliminating viruses and bacteria. (Almost all deep ultraviolet radiation from the sun is absorbed in the ozone layer and atmosphere, with very little reaching the surface of the earth)

What is UV-C (deep ultraviolet)?

■Comparison with conventional disinfecting light sources (mercury lamps)

Comparison with conventional disinfecting light sources (mercury lamps)

02Applying the knowledge cultivated in blue LEDs

Toyoda Gosei began research on blue LEDs in 1986 under the guidance of Professors Isamu Akasaki and Hiroshi Amano, who were awarded the Nobel Prize in Physics in 2014. We were the first in the world to successfully develop blue LEDs in 1991 and began mass producing them in 1995. Blue LEDs use gallium nitride and UV-C LEDs use aluminum nitride, both of which are main materials in nitride semiconductors. Since the principle of forming chips on a sapphire substrate is the same, the knowledge and technical abilities that Toyoda Gosei cultivated over many years in the development and production of blue LEDs is applied in the development of UV-C LEDs.

Blue LEDs
Blue LEDs

UV-C LEDs differ from blue LEDs in that the lens material diffuses light. Normally resin or glass is used for lenses, but because the transmittance of UV-C LEDs is low a special lens with high transparency called quartz glass is used. However, quartz glass has the property of absorbing light itself, making inefficient extraction of light an issue. Electricity is changed into greater amounts of light and as the light output is raised the sterilization effect becomes higher. Therefore, we are concentrating on development to improve the light extraction efficiency.
In 2021, the Ministry of the Environment adopted the development of highly efficient, long-life UV-C LEDs as a demonstration project. Toyoda Gosei is working together with Meijo University, Nagoya University, Tohoku University, University of Tokyo, and WOTA Corporation in an industry-government-academia project. Professor Hiroshi Amano, with whom Toyoda Gosei worked in the past on the research and development of blue LEDs, is also participating. We look forward eagerly to project results that will help bring forward the day mercury lamps can be replaced.

UV-C LED
UV-C LED

03Technology that applies LEDs

Toyoda Gosei is also dedicated to product development using UV-C LEDs. One such product is water purification units. To effectively purify water with UV-C, the way the water flows (fluidity) and the light irradiation methods are key aspects. We applied the fluid analysis technology we cultivated in the plastic molding of automotive parts, lengthened the water retention time inside the unit, and studied the structural design and light reflectance for the effective irradiation of UV-C light. Since current UV-C LEDs produce much heat, heat dissipation was also considered and a structure that cools LEDs with water passing through the inside was adopted.
As a result, both a high disinfecting performance that can disinfect eight liters of water per minute and a compact size that fits in the palm of your hand, at one-third the size of previous products, were achieved. These units can be installed in limited spaces, and are used in Eco-cute heat pump water heaters with a disinfecting function.
In April 2024, we developed UV-C LEDs that achieved light output at the 200 milliwatt level on a single chip. The LED device structure was improved, the amount of light that could be extracted was increased about four-fold, and the sterilization capacity was raised three-fold. Sample sales have begun in Japan and internationally, and applications are being expanded with use in water, air and more. We will expand the fields of use of UV-C LEDs, including future replacement of mercury lamps, and contribute to more hygienic, secure, and safe living.

Voice of developer

Delivering clean water worldwide with UV-C LEDs

In many developing countries and other regions, water infrastructure is underdeveloped. In the future, we hope to deliver water purification plants using UV-C LEDs to people facing water problems. In places where it is difficult to install large facilities, people can first simply attach a small water purification unit to faucets in order to safely use water. Through product development, I hope to help create societies where everyone can access clean water.

Yusuke Toyoda, General Manager, Life Solution Engineering Division 1

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